Dipole moment
From Wikipedia, the free encyclopediaDipole moment may refer to:- Electric dipole moment, the measure of the electrical polarity of a system of charges
- Transition dipole moment, the electrical dipole moment in quantum mechanics
- Molecular dipole moment, the electric dipole moment of a molecule.
- Bond dipole moment, the measure of polarity of a chemical bond
- Electron electric dipole moment, the measure of the charge distribution within an electron
- Magnetic dipole moment, the measure of the magnetic polarity of a system of charges
- Electron magnetic moment
- Nuclear magnetic moment, the magnetic moment of an atomic nucleus
- Topological dipole moment, the measure of the topological defect charge distribution
- The first order term (or the second term) of the multipole expansion of a function
- The dielectric constant of a solvent is the measure of its capacity to break the covalent molecules into ions
From Wikipedia, the free encyclopedia
Dipole moment may refer to:
- Electric dipole moment, the measure of the electrical polarity of a system of charges
- Transition dipole moment, the electrical dipole moment in quantum mechanics
- Molecular dipole moment, the electric dipole moment of a molecule.
- Bond dipole moment, the measure of polarity of a chemical bond
- Electron electric dipole moment, the measure of the charge distribution within an electron
- Magnetic dipole moment, the measure of the magnetic polarity of a system of charges
- Electron magnetic moment
- Nuclear magnetic moment, the magnetic moment of an atomic nucleus
- Topological dipole moment, the measure of the topological defect charge distribution
- The first order term (or the second term) of the multipole expansion of a function
- The dielectric constant of a solvent is the measure of its capacity to break the covalent molecules into ions
See also[edit]
Transition dipole moment
From Wikipedia, the free encyclopedia
The Transition dipole moment or Transition moment, usually denoted
for a transition between an initial state,
, and a final state,
, is the electric dipole moment associated with the transition between the two states. In general the transition dipole moment is acomplex vector quantity that includes the phase factors associated with the two states. Its direction gives the polarization of the transition, which determines how the system will interact with an electromagnetic wave of a given polarization, while the square of the magnitude gives the strength of the interaction due to the distribution of charge within the system. The SI unit of the transition dipole moment is the Coulomb-meter (Cm); a more conveniently sized unit is the Debye (D).



Contents
[hide]Definition[edit]
A single charged particle[edit]
For a transition where a single charged particle changes state from
to
, the transition dipole moment
is



where q is the particle's charge, r is its position, and the integral is over all space (
is shorthand for
). The transition dipole moment is a vector; for example its x-component is


In other words, a transition dipole moment is simply an off-diagonal matrix element of the position operator, multiplied by the particle's charge.
Multiple charged particles[edit]
When the transition involves more than one charged particle, the transition dipole moment is defined in an analogous way to an electric dipole moment: The sum of the positions, weighted by charge. If the ith particle has charge qi and position operator ri, then the transition dipole moment is:
In terms of momentum[edit]
For a single, nonrelativistic particle of mass m, in zero magnetic field, the transition dipole moment can alternatively be written in terms of the momentum operator, using the relationship[1]
This relationship can be proven starting from the commutation relation between position x and the Hamiltonian H:
Then
However, assuming that ψa and ψb are energy eigenstates with energy Ea and Eb, we can also write
Similar relations hold for y and z, which together give the relationship above.
Analogy with a classical dipole[edit]
Main article: Electric dipole moment
A basic, phenomenological understanding of the transition dipole moment can be obtained by analogy with a classical dipole. While the comparison can be very useful, care must be taken to ensure that one does not fall into the trap of assuming they are the same.
In the case of two classical point charges,
and
, with a displacement vector,
, pointing from the negative charge to the positive charge, the electric dipole moment is given by



.
In the presence of an electric field, such as that due to an electromagnetic wave, the two charges will experience a force in opposite directions, leading to a net torque on the dipole. The magnitude of the torque is proportional to both the magnitude of the charges and the separation between them, and varies with the relative angles of the field and the dipole:
.
Similarly, the coupling between an electromagnetic wave and an atomic transition with transition dipole moment
depends on the charge distribution within the atom, the strength of the electric field, and the relative polarizations of the field and the transition. In addition, the transition dipole moment depends on the geometries and relative phases of the initial and final states.

Origin[edit]
When an atom or molecule interacts with an electromagnetic wave of frequency
, it can undergo a transition from an initial to a final state of energy difference
through the coupling of the electromagnetic field to the transition dipole moment. When this transition is from a lower energy state to a higher energy state, this results in the absorption of a photon. A transition from a higher energy state to a lower energy state results in the emission of a photon. If the charge,
, is omitted from the electric dipole operator during this calculation, one obtains
as used in oscillator strength.




Applications[edit]
The transition dipole moment is useful for determining if transitions are allowed under the electric dipole interaction. For example, the transition from a bonding
orbital to an antibonding
orbital is allowed because the integral defining the transition dipole moment is nonzero. Such a transition occurs between an even and an odd orbital; the dipole operator is an odd function of
, hence the integrand is an even function. The integral of an odd function over symmetric limits returns a value of zero, while for an even function this is not necessarily the case. This result is reflected in the parity selection rule forelectric dipole transitions. The transition moment integral



,
of an electronic transition within similar atomic orbitals, such as s-s or p-p, is forbidden due to the triple integral returning an ungerade (odd) product. Such transitions only redistribute electrons within the same orbital and will return a zero product. If the triple integral returns a gerade (even) product, the transition is allowed.
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